{"id":49,"date":"2020-03-27T16:22:14","date_gmt":"2020-03-27T20:22:14","guid":{"rendered":"http:\/\/totesa.website\/faculty\/?page_id=49"},"modified":"2025-05-08T17:29:49","modified_gmt":"2025-05-08T21:29:49","slug":"publications","status":"publish","type":"page","link":"https:\/\/sites.wp.odu.edu\/thelambertgroup\/publications\/","title":{"rendered":"Publications"},"content":{"rendered":"\n
\"\"<\/a><\/figure>\n\n\n\n

2<\/b>8. <\/strong>Stephens, S. M. and Lambert, K. M. <\/strong>“The Importance of Atomic Charges for Predicting Site-Selective Ir-, Ru-, and Rh-Catalyzed C\u2013H Borylations” J. Org. Chem.<\/em> 2025<\/strong>, 90, 17, 6000\u20136012.<\/p>\n\n\n

\n
\"\"<\/a><\/figure><\/div>\n\n\n

27. <\/strong> Pote, A. R.; Weierbach, S. M.; Peczuh, M. W.; Lambert, K. M.<\/strong> “Advancements in the synthesis of polyoxygenated oxepanes and thiepanes for applications to natural products” Org. Chem. Front. <\/em>2024<\/strong>, 11, 3729-3776. [link<\/a>]<\/p>\n\n\n

\n
\"\"<\/a><\/figure><\/div>\n\n\n

26. <\/strong> Phadnis, N; Molen, J. A.; Stephens, S. M.; Weierbach, S. M.; Lambert, K. M.<\/strong>; Milligan, J. A. “Green Oxidation of Aromatic Hydrazide Derivatives Using an Oxoammonium Salt” J. Org. Chem.<\/em> 2024<\/strong>, 89, 8, 5841-5845. [link<\/a>]<\/p>\n\n\n

\n
\"\"<\/a><\/figure><\/div>\n\n\n
\n
\n

25. <\/strong> Bray, J. M.; Stephens, S. M.; Weierbach, S. M.; Vargas, K.; Lambert, K. M.<\/strong> “Recent advancements in the use of Bobbitt’s salt and 4-acetamido TEMPO” Chem. Commun.<\/em> 2023<\/strong>, 59, 14063. [link<\/a>]<\/p>\n<\/div>\n<\/div>\n\n\n\n

\n
\"\"<\/a><\/figure>\n<\/figure>\n\n\n\n

24.<\/strong> Stephens, S. M.; Bray, J. M.; Weierbach, S. M.; Adornato, G. M.; Schrider, J. A., Lambert, K. M.<\/strong> “Facile Access to 1,3-Bis(boryl) Dienes to Build Molecular Complexity Through Cycloadditions” Tetrahedron Lett<\/em>. 2023<\/strong>, 117<\/em>, 154381. [Link<\/a>]<\/p>\n\n\n\n

\n
\"\"<\/a><\/figure>\n<\/figure>\n\n\n\n

23.<\/strong> Lewis, S. G.; Dadum, A. G.; McLean, D.; Buenavista, J.; Myers, J.; Lambert, K. M.<\/strong>; J. Fair “Chemoselective Oxidation of Alcohols in the Presence of Amines Using an Oxoammonium Salt” Tetrahedron<\/em> 2023<\/strong>, 131<\/em>, 133226. [Link<\/a>]<\/p>\n\n\n

\n
\"\"<\/a><\/figure><\/div>\n\n\n

22.<\/strong> Weierbach, S. M.; Reynolds, R. P.; Stephens, S. M.; Vlasakakis, K. V.; Ritter, R. T.; White, O. M.; Patel, N. H.; Hayes, E. C.; Dunmire, S.; Lambert, K. M.<\/strong> “Chemoselective Oxidation of Thiols with Oxoammonium Cations” J.<\/em> Org. Chem.<\/em> 2023<\/strong>, 88,11392-11410. [Link<\/a>]<\/p>\n\n\n

\n
\"\"<\/a><\/figure><\/div>\n\n\n

21.<\/strong> Lambert, K. M.<\/strong>; Kelly, C.; Milligan, J.; Tilley, L.; Reynolds, R. P.; McGuire, K. P.; Anzalone, L.; Del Sesto, K.; Walsh, S. “A practical Oxidation Experiment for Undergraduate Students: Bobbitt’s Salt as a “Green” Alternative” J. Chem. Educ.<\/em> 2022<\/strong>, 99, 9, 3249\u20133258. [Link<\/a>] <\/p>\n\n\n\n

\n
\"\"<\/figure><\/div>\n\n\n

20.   <\/strong>Kaetzel, N. D.; Lambert, K. M.*<\/strong>; Kelly, C. B. \u201cOxidation of Aldehydes to Nitriles with an Oxoammonium Salt: Preparation of Piperonylnitrile\u201d Org. Synth.<\/em> 2020<\/strong>, 97<\/em>, 294\u2013313. [Link<\/a>]<\/p>\n<\/div><\/div>\n\n\n\n

Prior to ODU<\/strong><\/p>\n\n\n

\n
\"\"<\/a><\/figure><\/div>\n\n\n

19.<\/strong> Jackson, A. C.; Olsen J. T.; Sundstrom, S.; Lambert, K. M.<\/strong>; Wood, J. L. “A Ring Expansion Approach To N-oxy-2,5-diketopiperazines” Tetrahedron Lett.<\/em> 2022<\/strong>, 99<\/em>, 153851\u2013153853. [Link<\/a>]<\/p>\n\n\n

\n
\"Graphical<\/figure><\/div>\n\n\n

18.   <\/strong>Komine, K.; Lambert, K. M.<\/strong>; Savage, Q. R.; Cox, J. B.; Wood, J. L. \u201cSynthetic Studies Toward Longeracemine: A SmI2-mediated Spirocyclization and Rearrangement Cascade to Construct the 2-Azabicyclo[2.2.1]heptane Framework\u201d Chem. Sci.<\/em> 2020<\/strong>, 11<\/em>, 9488\u20139493. <\/em>[Link<\/a>]<\/p>\n\n\n

\n
\"\"<\/a><\/figure><\/div>\n\n\n

17.   Lambert, K. M.<\/strong>; Cox, J. B.; Liu, L.; Jackson, A. C.; Wiberg, K. B.; Wood, J. L. \u201cTotal Synthesis of (\u00b1)\u2010Phyllantidine: Development and Mechanistic Evaluation of a Ring Expansion for Installation of Embedded Nitrogen\u2010Oxygen Bonds\u201d Angew. Chem.<\/em> 2020<\/strong>, 59<\/em>, 9757\u20139766. [Link<\/a>]<\/p>\n\n\n

\n
\"\"<\/figure><\/div>\n\n\n

16.   Lambert, K. M.*<\/strong>; Medley, A. W.; Jackson, A. C.; Markham, L. E.; Wood, J. L. \u201cSynthesis of Chiral Tetramic Acids: Preparation of (S<\/em>)-5-Benzylpyrrolidine-2,4-dione from L<\/em>-phenylalanine Methyl Ester Hydrochloride\u201d Org. Synth. <\/em>2019<\/strong>, 96<\/em>, 528-585. [Link<\/a>]<\/p>\n\n\n

\n
\"Image<\/figure><\/div>\n\n\n

15. <\/strong>  Gayler, K. M.; Lambert, K. M.<\/strong>; Wood, J. L. \u201cSynthetic studies towards the penicisulfuranols: Synthesis of an advanced spirocyclic diketopiperazine intermediate\u201d Tetrahedron<\/em> 2019<\/strong>, 75<\/em>, 3154\u20133159. [Link<\/a>]<\/p>\n\n\n

\n
\"\"<\/figure><\/div>\n\n\n

14.<\/strong>   Wiberg, K. B.; Bailey, W. F.; Lambert, K. M.<\/strong> \u201cUnrecognized Intramolecular and Intermolecular Attractive Interactions between Fluorine-Containing Motifs and Ether, Carbonyl, and Amino Moieties\u201d J.<\/em> Org. Chem.<\/em> 2019<\/strong>, 84<\/em>, 15463\u201315469. [Link<\/a>]<\/p>\n\n\n

\n
\"\"<\/figure><\/div>\n\n\n

13.   Lambert, K. M.<\/strong>; Eldirany, S. A.; Bobbitt, J. M.; Bailey, W. F. \u201cCatalytic, Metal-Free Oxidation of Primary Amines to Nitriles\u201d Org. Synth.<\/em> 2018<\/strong>, 95<\/em>, 60\u201379. [Link<\/a>]<\/p>\n\n\n

\n
\"Abstract<\/figure><\/div>\n\n\n

12.<\/strong>   Wiberg, K. B.; Bailey, W. F.; Lambert<\/strong>, K. M.; Stempel, Z. D. \u201cThe Anomeric Effect: It\u2019s Complicated\u201d J. Org. Chem. <\/em>2018<\/strong>, 83<\/em>, 5242\u20135255. [Link<\/a>]<\/p>\n\n\n

\n
\"\"<\/figure><\/div>\n\n\n

11.   Lambert, K. M.<\/strong>; Stempel, Z. D.; Wiberg, K. B.; Bailey, W. F. \u201cExperimental Demonstration of a Sizeable Nonclassical CH\u2219\u2219\u2219G Hydrogen Bond in Cyclohexane Derivatives: Stabilization of an Axial Cyano Group\u201d Org. Lett.<\/em> 2017<\/strong>, 19<\/em>, 6408\u20136411. [Link<\/a>]<\/p>\n\n\n

\n
\"Book<\/figure><\/div>\n\n\n

10.   <\/strong>Bailey, W. F.; Lambert, K. M.<\/strong> \u201cThe Importance of Electrostatic Interactions on the Conformational Behavior of Substituted 1,3-Dioxanes: The Case of 5-Phenyl-1,3-dioxane.\u201d In Stereochemistry and Global Connectivity:<\/em> The Legacy of Ernest L. Eliel Volume 2<\/em>; Cheng, H. N.; Maryanoff, C. A.; Miller, B. D.; Schmidt, D. G., Eds.;ACS Symposium Series Vol.1258; American Chemical Society: Washington, DC, 2017<\/strong>; Chapter 2,  pp 19\u201326. [Link<\/a>]<\/p>\n\n\n

\n
\"Abstract<\/figure><\/div>\n\n\n

9.<\/strong>   Lambert, K. M.<\/strong>*;Stempel, Z. D.; Kiendzior, S. M.; Bartelson, A. L.; Bailey, W. F. \u201cEnhancement of the Oxidizing Power of an Oxoammonium Salt by Modification of a Distal Group\u201d J. Org. Chem.<\/em> 2017<\/strong>, 82<\/em>, 11440\u201311446. [Link<\/a>]<\/p>\n\n\n

\n
\"\"<\/figure><\/div>\n\n\n

8.   <\/strong>Bailey, W. F.; Lambert, K. M.<\/strong>; Stempel, Z. D.; Wiberg, K. B.; Mercado, B. Q. \u201cControlling the Conformational Energy of a Phenyl Group by Tuning the Strength of a Nonclassical CH\u2219\u2219\u2219O Hydrogen Bond: The Case of 5-Phenyl-1,3-dioxane” J. Org. Chem.<\/em> 2016<\/strong>, 81<\/em>, 12116\u201312127. [Link<\/a>] This article was selected as a Featured Article for J. Org. Chem.<\/em><\/p>\n\n\n

\n
\"\"<\/figure><\/div>\n\n\n

7.   <\/strong>Bartelson, A. L.; Lambert, K. M.<\/strong>; Bobbitt, J. M.; Bailey, W. F. \u201cRecent Developments in the Nitroxide-Catalyzed Oxidation of Amines: Preparation of Imines and Nitriles\u201d Chem. Cat. Chem. <\/em>2016<\/strong>, 8<\/em>, 3421\u20133430. [Link<\/a>]<\/p>\n\n\n

\n
\"\"<\/figure><\/div>\n\n\n

6.   Lambert, K. M.<\/strong>; Bobbitt, J. M.; Eldirany, S. E.; Kissane, L. E.; Sheridan, R. K.; Stempel, Z. D.; Sternberg, F. H.; Bailey, W. F. \u201cMetal-Free Oxidation of Primary Amines to Nitriles through Coupled Catalytic Cycles.\u201d Chem. Eur. J<\/em>. 2016<\/strong>, 22<\/em>, 5156\u20135159. [Link<\/a>] This work was featured in Synform 2016<\/strong>, 07, A100\u2013A103.<\/em> [Link<\/a>]<\/p>\n\n\n

\n
\"\"<\/figure><\/div>\n\n\n

5.<\/strong>   Wiberg, K. B.; Lambert, K. M.<\/strong>; Bailey, W. F.; \u201cThe Role of CH\u2219\u2219\u2219O Coulombic Interactions in Determining Rotameric Conformations of Phenyl Substituted 1,3-Dioxanes and Tetrahydropyrans.\u201d J. Org. Chem. <\/em>2015<\/strong>, 80, <\/em>7884\u20137889. [Link<\/a>]<\/p>\n\n\n

\n
\"\"<\/figure><\/div>\n\n\n

4.   <\/strong>Bailey, W. F.; Lambert, K. M.<\/strong>; Wiberg, K. B.; Mercado, B. Q. \u201cEffect of Remote Aryl Substituents on the Conformational Equilibria of 2,2,-Diaryl-1,3-dioxanes: Importance of Electrostatic Interactions.\u201d J. Org. Chem. <\/em>2015<\/strong>, 80<\/em>, 4108\u20134115. [Link<\/a>]<\/p>\n\n\n

\n
\"\"<\/figure><\/div>\n\n\n

3.   <\/strong>Kelly, C. B.; Lambert, K. M.<\/strong>; Mercadante, M. A.; Ovian, J. M.; Bailey, W. F.; Leadbeater, N. E. \u201cAccess to Nitriles from Aldehydes Mediated by an Oxoammonium Salt.\u201d  Angew. Chem. Int. Ed. <\/em>2015<\/strong>, 54<\/em>, 4241\u20134245. [Link<\/a>] This work was featured inOrg. Process Res. Dev. 2015<\/strong>, 19, 596\u2013610.<\/em> [Link<\/a>]<\/p>\n\n\n

\n
\"Graphical<\/figure><\/div>\n\n\n

2.<\/strong>   Wiberg, K. B.; Lambert, K. M.<\/strong>; Bailey, W. F. \u201cRotamers of Phenyl Substituted 1,3-Dioxanes and Tetrahydropyrans: Importance of CH\u2219\u2219\u2219O Coulombic Interactions.\u201d Tetrahedron Lett<\/em>. 2015<\/strong>, 56<\/em>, 3438\u20133440. [Link<\/a>]<\/p>\n\n\n\n

\n
\"\"<\/figure><\/div><\/figure>\n\n\n\n

1.\u00a0\u00a0 Lambert, K. M.<\/strong>; Bobbitt, J. M.; Eldirany, S. A.; Wiberg, K. B; Bailey, W. F. \u201cFacile Oxidation of Primary \u00a0Amines to Nitriles Using an Oxoammonium Salt.\u201d Org. Lett. <\/em>2014<\/strong>, 16<\/em>, 6484\u20136487. [Link<\/a>]<\/p>\n","protected":false},"excerpt":{"rendered":"

28. Stephens, S. M. and Lambert, K. M. “The Importance of Atomic Charges for Predicting Site-Selective Ir-, Ru-, and Rh-Catalyzed C\u2013H Borylations” J. Org. Chem. 2025, 90, 17, 6000\u20136012. 27. Pote, A. R.; Weierbach, S. M.; Peczuh, M. W.; Lambert, K. M. “Advancements in the synthesis of polyoxygenated oxepanes and thiepanes for applications to natural […]<\/p>\n","protected":false},"author":17052,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"open","template":"","meta":{"footnotes":""},"jetpack_sharing_enabled":true,"_links":{"self":[{"href":"https:\/\/sites.wp.odu.edu\/thelambertgroup\/wp-json\/wp\/v2\/pages\/49"}],"collection":[{"href":"https:\/\/sites.wp.odu.edu\/thelambertgroup\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/sites.wp.odu.edu\/thelambertgroup\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/sites.wp.odu.edu\/thelambertgroup\/wp-json\/wp\/v2\/users\/17052"}],"replies":[{"embeddable":true,"href":"https:\/\/sites.wp.odu.edu\/thelambertgroup\/wp-json\/wp\/v2\/comments?post=49"}],"version-history":[{"count":6,"href":"https:\/\/sites.wp.odu.edu\/thelambertgroup\/wp-json\/wp\/v2\/pages\/49\/revisions"}],"predecessor-version":[{"id":1550,"href":"https:\/\/sites.wp.odu.edu\/thelambertgroup\/wp-json\/wp\/v2\/pages\/49\/revisions\/1550"}],"wp:attachment":[{"href":"https:\/\/sites.wp.odu.edu\/thelambertgroup\/wp-json\/wp\/v2\/media?parent=49"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}